King Gurumes

King Gurumes is the main antagonist of Movie 1, Curse of the Blood Rubies. At the climax of the film, Shenron is summoned whilst the seven Dragon Balls are gathered inside Gurumes stomach; the ray of light emitted by the Balls during the summoning process explodes through his mouth, destroying the upper floors of his castle. It is also shown that Shenron's actions have re-granted Gurumes his human form, and ultimately his appetite is cured when Penny hands him a common apple, its simplicity shocking the king.
His henchmen are:

• Bongo, who is crushed by King Gurumes.
• Raven, who is a pretty girl.

Lucifer

Main article: Lucifer

Lucifer

Lucifer is the main antagonist of Movie 2, Sleeping Princess in Devil's Castle. Bulma screamed out to Goku what it was about to do, and he blasted the cannon with a Kamehameha. This did not destroy the cannon, but knocked it off its foundation and pointed straight at Lucifer. The cannon fired right as he looked down the barrel, and the massive energy wave killed him.
His henchmen are:

• Igor, who is defeated by Yamcha.
• Ghastel, who is killed by a swamp monster.

Minister Shen

Main article: Master Shen

Minister Shen

Master Shen is the main antagonist in the movie Dragon Ball: Mystical Adventure. He is part of a plan with his apprentice Tien Shinhan and General Tao to take over the kingdom of Mifan, ruled by Emperor Chiaotzu. Near the end of the movie, as Tien refuses Shen's order to kill Chiaotzu, Shen says he will kill Chiaotzu himself but he is sent flying off Mifan Castle by Tien's Tri-Beam.
His henchmen are the Mifan Army, with notably:

• General Tao, who is defeated by Goku, Arale Norimaki, and the Gatchans,.
• Lieutenant Blue, who is executed by General Tao.
• Major Metallitron, whose head is removed by Goku's Kamehameha several times in the film. 

http://dragonball.wikia.com/wiki/List_of_Film_Villains

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